journals.iop.org home page electronic journals * User guide   * Site map   | Quick Search:Help  
Journal of Physics: Conference Series
Athens/Institutional login
IOP login: Password:   
Create account | Alerts | Contact us
Journals Home | Journals List | EJs Extra | This Journal | Search | Authors | Referees | Librarians | User Options | Help |

EXAFS study of filled skutterudites RT4Sb12(R:La,Ce,Pr,Nd,Sm, T:Fe,Ru,Os)

Kiyofumi Nitta et al 2009 J. Phys.: Conf. Ser. 190 012098 (4pp)   doi: 10.1088/1742-6596/190/1/012098  Help

   PDF (602 KB) | References

Kiyofumi Nitta1, Yusuke Omori2, Takafumi Miyanaga2, Katsuhiko Takegahara2, Hitoshi Sugawara3, Daisuke Kikuchi4 and Hideyuki Sato4
1 KEK-PF, Tsukuba, Ibaraki 305–0801, Japan
2 Department of Advanced Physics, Hirosaki University, Hirosaki, Aomori 036–8561, Japan
3 Faculty of Integrated Arts and Sciences, Tokushima University, Tokushima 770–8502, Japan
4 Graduate School of Science, Tokyo Metropolitan University, Hachioji, Tokyo 192–0397, Japan
E-mail: nittak@post.kek.jp

Abstract. The filled skutterudites RT4X12 (R: rare-earth, T: transition metal, X: pnictogen) show a variety of intriguing features by changing the combination of R, T, and X. Among them, some compounds shows characteristic feature called "rattling" that is considered as anharmonic oscillation or off-centered motion of rare-earth ions accommodated in the icosahedron cages made from pnictogen and "rattling" is suggested to contribute to the various features of this system. We applied extended X-ray absorption fine structure (EXAFS) on this system to clarify the microscopic mechanism of "rattling" motion [1]. Temperature dependence of EXAFS thermal (Debye-Waller) factors of R-Sb and T-Sb atomic pairs were analyzed by Einstein model. Thermal oscillation and static distortion are analyzed independently. From this study, we could know systematic information about "rattling" as a large amplitude oscillation of rare-earth ions and static distortion that has two types of cage space dependence.

Bookmark and Share Post to CiteUlike | Post to Connotea | Post to Bibsonomy

 


Find related articles





Article options

Authors & Referees

 
Content finder
  Full Search
  Help


  
Setup information is available for Adobe Acrobat.
EndNote, ProCite ® and Reference Manager ® are registered trademarks of ISI Researchsoft.
Copyright © Institute of Physics and IOP Publishing Limited 2009.
Use of this service is subject to compliance with the Terms and Conditions of use. In particular, reselling and systematic downloading of files is prohibited.
Help: Cookies | Data Protection. Privacy policy Disclaimer