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Predetermining acceptable noise limits of EXAFS spectra in the limit of stochastic noise

Yung-Jin Hu et al 2009 J. Phys.: Conf. Ser. 190 012029 (4pp)   doi: 10.1088/1742-6596/190/1/012029  Help

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Yung-Jin Hu1 and Corwin H Booth2
1 Nuclear Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720, USA
2 Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720, USA
E-mail: YHu@lbl.gov

Abstract. The effect of stochastic noise on Extended X-ray Absorption Fine Structure (EXAFS) data measurement, analysis, and fitting is discussed. Stochastic noise reduces the ability to uniquely fit a calculated model to measured EXAFS data. Such noise can be reduced by common methods that increase the signal-to-noise ratio; however, these methods are not always practical. Therefore, predetermined, quantitative knowledge of the level of acceptable stochastic noise when fitting for a particular model system is essential in maximizing the chances of a successful EXAFS experiment and minimizing wasted beamtime. This paper outlines a method to estimate, through simulation, the acceptable level of stochastic noise in EXAFS spectra that still allows a successful test of a proposed model compound.

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