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Fabrication of nanopore arrays and ultrathin silicon nitride membranes by block-copolymer-assisted lithography

Ana-Maria Popa et al 2009 Nanotechnology 20 485303 (11pp)   doi: 10.1088/0957-4484/20/48/485303  Help

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Ana-Maria Popa1,2,3, Philippe Niedermann1, Harry Heinzelmann1, Jeffrey A Hubbell2 and Raphaël Pugin1
1 Centre Suisse d'Electronique et de Microtechnique SA, Jaquet Droz 1, CH-2000 Neuchâtel, Switzerland
2 Institute of Bioengineering and Institute of Chemical Sciences and Engineering, Ecole Polytechnique Fédérale de Lausanne (EPFL), CH-1015 Lausanne, Switzerland
3 Present address: Laboratory for Protection and Physiology, Empa, CH-9014 St Gallen, Switzerland
E-mail: ana-maria.popa@empa.ch and rpu@csem.ch

Abstract. Here we show a method for patterning a thin metal film using self-assembled block-copolymer micelles monolayers as a template. The obtained metallic mask is transferred by reactive ion etching in silicon oxide, silicon and silicon nitride substrates, thus fabricating arrays of hexagonally packed nanopores with tunable diameters, interspacing and aspect ratios. This technology is compatible with integration into a standard microtechnology sequence for wafer-scale fabrication of ultrathin silicon nitride nanoporous membranes with 80 nm mean pore diameter.

Print publication: Issue 48 (2 December 2009)
Received 14 August 2009, in final form 28 September 2009
Published 30 October 2009

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