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DNA-assisted formation of quasi-nanowires from fluorescent CdSe/ZnS nanocrystals

Vitali Stsiapura et al 2006 Nanotechnology 17 581-587   doi: 10.1088/0957-4484/17/2/040  Help

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Vitali Stsiapura1,2, Alyona Sukhanova1, Alexander Baranov3, Mikhail Artemyev4, Olga Kulakovich2, Vladimir Oleinikov5, Michel Pluot1, Jacques H M Cohen1 and Igor Nabiev1,6
1 EA no 3798 'Détection et Approches Thérapeutiques Nanotechnologiques dans les Mécanismes Biologiques de Défense', Université de Reims Champagne-Ardenne, 51100 Reims, France
2 Yanka Kupala State University, 230023 Grodno, Belarus
3 S I Vavilov State Optical Institute, 199034 St-Petersburg, Russia
4 Institute for Physico-Chemical Problems, Belarussian State University, 220080 Minsk, Belarus
5 Shemyakin-Ovchinnikov Institute of Bioorganic Chemistry, Russian Academy of Sciences, 117997 Moscow, Russia
6 Author to whom any correspondence should be addressed
E-mail: igor.nabiev@univ-reims.fr

Abstract. Highly ordered quasi-nanowires from fluorescent semiconductor CdSe/ZnS spherical (quantum dots) or rod-like (quantum rods) nanoparticles were produced using DNA as a template. Positively charged nanoparticles were fixed along the negatively charged DNA backbone by electrostatic interaction. After incubation of the solution of DNA and nanoparticles at different stoichiometric ratios the complexes were applied to the hydrophobic surface and stretched using the molecular combing technique. Here, we demonstrate that fluorescent patterns with desirable morphology and properties can be formed by varying the nanoparticle charge and shape and their stoichiometry in the complex with DNA.

Print publication: Issue 2 (28 January 2006)
Received 5 September 2005, in final form 28 October 2005
Published 3 January 2006

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