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Understanding electron flow in conducting polymer films: injection, mobility, recombination and mesostructure

A M Stoneham et al 2002 J. Phys.: Condens. Matter 14 9877-9898   doi: 10.1088/0953-8984/14/42/304  Help

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A M Stoneham1, M M D Ramos2, A M Almeida2, H M G Correia2, R M Ribeiro2, H Ness3 and A J Fisher1
1 Department of Physics and Astronomy, University College London, Gower Street, London WC1E 6BT, UK
2 Departamento de Fisica, Universidade do Minho, Braga 4710-057, Portugal
3 CEA-Saclay, DSM/DRECAM/SPCSI, Bât. 462, F-91191 Gif sur Yvette, France

Abstract. We survey the current state of models for electronic processes in conducting polymer devices, especially light-emitting diodes. We pay special attention to several processes that have been somewhat neglected in the previous literature: charge injection from electrodes into a polymer sample, mobility of charge-or energy-carrying defects within a single molecule and (more briefly) transfer of carriers between molecules and the interaction between the charge transport and the mesostructure of the polymer. Within all these areas substantial progress has been made in recent years in elucidating the important physics, but further progress is needed to make quantitative contact with experiment.

Print publication: Issue 42 (28 October 2002)
Received 12 August 2002
Published 11 October 2002

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