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Influence of intermediate states on photoelectron spectra

A Pohl et al 2001 J. Phys. B: At. Mol. Opt. Phys. 34 4969-4981   doi: 10.1088/0953-4075/34/24/301  Help

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A Pohl1, P-G Reinhard1 and E Suraud2
1 Institut für Theoretische Physik, Universität Erlangen, Staudtstrasse 7, D-91058 Erlangen, Germany
2 Laboratoire de Physique Quantique, Université Paul Sabatier, 118 Route de Narbonne, F-31062 Toulouse Cédex, France

Abstract. We investigate the information contained in the photoelectron spectra (PES) of electrons emitted from an atom, molecule, or cluster under the influence of a laser pulse. Basic patterns are evaluated in a simple potential well model. The results are corroborated by realistic applications to the cluster Na9+ calculated within a time-dependent density functional formalism. The final PES are composed from an interplay between features of the laser pulse and spectral properties of the emitting system. We discuss the mutual influences and the possibilities for disentangling the various effects.

Print publication: Issue 24 (28 December 2001)
Received 21 June 2001, in final form 10 October 2001
Published 10 December 2001

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