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2009 Supercond. Sci. Technol. 22 125016 (6pp) doi: 10.1088/0953-2048/22/12/125016
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Abstract.
The superconducting properties of YBCO (yttrium barium copper oxide) coated
conductors (CCs) are strongly dependent on their oxygen content. Degradation of the
superconducting properties of a YBCO CC can occur due to a phase/structure transition
caused by the oxygen diffusion out of the YBCO during heat-treatment or soldering, which
is an inevitable process during the creation of a superconducting joint. Such variations in
phase/structure are generally functions of temperature and oxygen partial pressure (PO2). Therefore, in order for a superconducting joint of YBCO CC to be feasible,
it is important to examine the changes in the microstructure and oxygen
diffusion behavior for YBCO CCs. This study examined the superconducting
properties of YBCO CCs before and after a heat-treatment under a reduced
PO2
followed by an oxygenation annealing process in an oxygen rich environment. Partial melting of
YBCO without melting of the silver stabilizer layer was obtained for a sample heat treated for 60 s
at 820 °C
and
Torr. The superconducting properties of the sample heat treated at
820 °C
were fully restored by an oxygenation annealing treatment for 15 h at
600 °C.
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