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Observation of a sample-dependent 37 K anomaly on the lattice parameters of strontium titanate

L. Arzel et al 2003 Europhys. Lett. 61 653-659   doi: 10.1209/epl/i2003-00121-4  Help

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L. Arzel1,2, B. Hehlen1, F. Dénoyer3, R. Currat2, K.-D. Liss4 and E. Courtens1
1 Laboratoire des Verres, UMR 5587 CNRS, Université Montpellier II F-34095 Montpellier Cedex 5, France
2 Institut Laue-Langevin - BP 156, F-38042 Grenoble Cedex 9, France
3 Laboratoire de Physique des Solides, UMR 8502 CNRS, Université Paris-Sud F-91405 Orsay Cedex, France
4 European Synchrotron Radiation Facility BP 220, F-38043 Grenoble Cedex, France

Abstract. The lattice parameters of tetragonal strontium titanate are determined to about 1 part in 106 with penetrating X-rays. While no peculiarity is detected in a bulk sample, a distinct anomaly at 37 K is observed in an optically polished thin platelet derived from the same single crystal. This suggests that the anomaly is related to a high density of dislocations. A possible mechanism is that dislocations stabilize transverse antiphase boundaries which undergo a ferroelectric transition near 37 K. If so, this transition stresses the boundaries which then strain the bulk leading to the observed anomaly.

PACS numbers: 61.50.Ks, 77.84.Dy, 61.10.-i

Print publication: Issue 5 (March 2003)
Received 5 August 2002, in final form and accepted for publication 16 December 2002

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