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A comment on the calculation of atomic energy levels in LS coupling using relativistic radial integrals

K G Dyall 1985 J. Phys. B: At. Mol. Phys. 18 L175-L177   doi: 10.1088/0022-3700/18/7/001  Help

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K G Dyall
Dept. of Chem., Monash Univ., Clayton North, Vic., Australia

Abstract. Relativistic effects have been included in non-relativistic term energies in some recent work by relating to non-relativistic radial integrals. It is seen that the need for a non-relativistic term energy is principally one of labelling the eigenstates of the atomic system according to some single-configuration coupling scheme, which could be achieved by a coupling transformation from the basic jj-coupled schemes used in relativistic atomic structure calculations.

Print publication: Issue 7 (14 April 1985)

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